SciencePlus

Why ice floats

Ice is water, yet it floats. The solid is less dense than the liquid because of how the molecules lock together.

Ice floating in water.
Photograph by liz west. CC BY 2.0. Wikimedia Commons. Ice floating in water.

Most substances shrink as they freeze. Water does the opposite near its freezing point. As liquid water cools towards 0°C it becomes denser, until about 4°C. Cool it further and it starts to expand again. When it freezes, it expands more.

The reason is the shape of the molecule and the hydrogen bonds between molecules. In ice, those bonds hold the molecules in an open crystal. The same number of molecules takes up more space than in the liquid, so a block of ice weighs less than the same volume of water.

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